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(1) Copper reacts with dilute nitric acid without heating to produce copper nitrate, NO and water. The ion reaction is 3cu+8h+2no3-= 3cu2+2no+4h2o to generate copper nitrate solution. It was observed that the solution turned blue, NO gas was generated, and NO reacted with oxygen to generate nitrogen dioxide. The gas in the flask changed from colorless to red, and the balloon became bigger.

So the answer is: no; 3Cu+8h++ 2 NO3-= 3c U2 ++ 2NO ↑+ 4H2O; The gas in the flask changed from colorless to red; Balloon inflation;

(2) A. Adding distilled water will slow down the reaction speed of nitric acid dilution, so A is wrong;

B. Sodium acetate will react with nitric acid to generate acetic acid, and the acid will change from strong acid to weak acid, and the reaction speed will be slow, so B is wrong;

C. The primary battery formed by graphite, metallic copper and nitric acid takes metallic copper as the negative electrode, which accelerates the reaction speed, so C is correct;

D. Adding AgNO3 _ 3 solution (a small amount), metallic copper will replace metallic silver. In the formed primary battery, metallic copper is the negative electrode, which speeds up the reaction, so D is correct;

So choose CD.

(3) Nitric oxide and nitrogen dioxide can be absorbed by water in a certain proportion to obtain nitric acid solution, so the gas is gradually reduced, and nitrogen oxides are converted into nitric acid to generate 4NO2+O2+2H2O ═ 4NO3, or 4NO+3O2+2H2O ═ 4NO3, so the answer is: NO2+O2+2H2O ═ 4NO3 (or 4NO

(4) ③ n (Cu) = 0.384g64g/mol = 0.006mol, from 3cu+8h+2no3-= 3cu2+2no = 4h2o, it can be known that the Cu oxidized by nitric acid is 0.01l×1.2mol/l×/kloc-.

According to 2Na2O2+2CO2═2Na2CO3+O2, 4NO+3O2+2H2O=4HNO3, 3cu+8h+2no3-= 3cu2+2no↑+4h2o, The total reaction is 2cu+4hno3+O2 ═ 2cu (NO3) 2+2h2o.n (O2) = 0.003mol× 22.4l/mol = 0.0672l = 67.2ml, where A contains air under standard conditions (oxygen accounts for one fifth) and the flask is 250mL, so oxygen accounts for (250ml).

Therefore, the answer is: 2na2o3+2co2 ═ 2n2co3+O2; 2cu+4hno3+o2═2cu(no3)2+2h2o; 38.4mL。