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Is the difference between I and Y in Mandarin vowels round or not?
The difference between I and Y in Mandarin vowels is not whether the lips are round or not.

There is no difference in pronunciation. There is no difference between the pronunciation of "Y" and "I" in Chinese Pinyin, but "Y" is neither an initial nor a vowel. According to the provisions of the Chinese Pinyin Scheme, when there is no initial in front, only the vowels in column I are written as yi (meaning), ya (elegance), ye (leaf), yao (Yao), you (worry), yan (smoke), yin (cause), yɑng (middle) and ying (English).