I don't know the specific style and weave of your clothes, so I can't give you the specific HS, but you can't choose one of the above three ingredients.

50% wool and 50% polyester should belong to polyester clothing.

60% wool and 40% polyester should belong to wool clothing.

10% wool and 90% polyester should belong to polyester clothing.

Therefore, 1 and 3 are one HS and 2 is another HS.